Base case: A tree containing a single node has 0 internal nodes and 1 leaf. Inductive step: If a proper binary tree with 0<=r<=k internal nodes has r+1 leaves, then a proper binary tree with k+1 internal nodes has k+2 leaves. Proof: Consider a proper binary tree T with k+1 internal nodes, k>=0. Since T is proper, it consists of a root plus two subtrees, each of which is also a proper binary tree. Call the left subtree T1, and the right subtree T2. T1 contains some number of internal nodes; call that number x. The root of T is also an internal node. The remainder of the internal nodes in T must be in T2, so T2 contains k+1-x-1 => k-x internal nodes. By the inductive hypothesis, T1 contains x+1 leaves and T2 contains k-x+1 leaves. Since all of the leaves in T are in either T1 or T2, T must contain x+1+k-x+1 => k+2 leaves.
Base case: A binary tree consisting of a single node contains 0 nodes with two children and 1 leaf. Inductive step: If a binary tree containing k nodes with two children has k+1 leaves, then a binary tree containing k+1 nodes with two children has k+2 leaves. Proof: Consider a binary tree T that has k nodes with two children, and by the inductive hypothesis has k+1 leaves. There are two ways to grow this tree: by adding a child to a leaf, or by adding a child to a node that already has one child. If you add a child to a leaf, neither the number of nodes with two children nor the number of leaves changes, so the property still holds. If you add a child to a node that already has one child, the number of nodes with two children increases by 1, to k+1, and the number of leaves increases by 1, to k+2.